CHENG Yangfan1, LIANG Haojian, SUN Tianyu, GUO Qingqing, SUN Kuankuan, LI Xiang
To solve the problem of low reaction rate and incomplete reaction of metal fuels, a core-shell structured composite energetic material, AP@TiH2, consisting of ammonium perchlorate (AP) particles coated with titanium hydride (TiH2) powder, was prepared by the solvent-nonsolvent method. The microstructure distribution and ignition combustion performance of this composite material were studied by characterization technique and laser ignition experiments. The results show that Ti is uniformly attached to the surface of massive ammonium perchlorate particles, and the AP@TiH2 composite material has brighter flame, larger reaction area, shorter combustion time and faster reaction rate. The addition of AP@TiH2 to solid propellants can effectively improve the ignition characteristics of the propellants, and improve the combustion performance. Compared with the traditional mechanical mixing methods, the temperature rise rate of AP@TiH2/HTPB propellant prepared by the solvent-nonsolvent method is faster, the average temperature of stable combustion stage is higher, the ignition delay time is reduced by about 10%, and the linear combustion rate is increased by about 11%. The coating structure reduced the mass and heat transfer distance between the fuel and oxidizer, and effectively improved the reaction rate and reaction completeness of the fuel. This fine control method is expected to provide a new way for the effective utilization of solid propellant energy.